Latest Group News
January 2025
We extend a warm welcome a new group member, Adam Carr. Adam joins us from the University of York (MSc Green Chemistry) to start his Ph.D. research. He will be working on a Leverhulme Trust funded project to develop the chemistry of our benzodiphosphaborolediide ligand (CEJ 2021), and expand on this novel motif to develop the broader ligand class. |
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A 3.5 year PhD studentship in potentially available from September 2025 as part of the Sussex EPSRC DLA competition. The project would focus on the synthesis of macrocyclic phosphanes with potential for molecular electronic applications, building on some of our recent work (J. Org. Chem. 2020). |
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July 2024
We still have a 3.5 year PhD studentship available in the group from September 2024; fully funded (UK students) on the Leverhulme Trust Project Grant "Heteroborolediides: A New Class of Donor-Acceptor Ligand". The project will build on our work with the benzodiphosphaborolediide (CEJ 2021) to expand and develop the synthetic route to access a range of related ligands and explore their coordination chemistry. Full details |
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We welcome Nathan to the group, whoi joins us for a summer project. Nathan, one of our second year undergraduates, joins us having secured a very competitive Kroto-Walton JRA studentships, one of four awarded in memory of Prof. Sir Harry Kroto and Dr David Walton, as part of the Sussex Junior Research Associate Scheme. Nathan's project will explore some of our cyaphide-derived chemistry, seeking to expand this toward previously inaccessible systems. |
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May 2024
Our latest paper is just accepted in Chem. Eur. J. and describes the first example of a monometallic bis(cyaphido) complex. Maddie estabilshed access to this novel compound from her 5-coordinate cyaphidic cation during her Ph.D.; Monte then picked up the project and obtained x-ray data. This is the first time two cyaphide ligand have been bound to a single metal centre, representing a significant step in establishing the versatility of the ligand in line with its carbonyl and cyanide analogues. Our computational studies, in collaboration with our colleague John Turner, also show that in addition to being a good σ-donor and π-acceptor, cyaphide also has a degree of π-donor character beyond that of cyanide. The work has been highlighted in ChemistryViews Magazine. |
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March 2024
PhD Studentship Available We have a 3.5 year PhD studentship available in the group from September 2024; fully funded (UK students) on the Leverhulme Trust Project Grant "Heteroborolediides: A New Class of Donor-Acceptor Ligand". The project will build on our work with the benzodiphosphaborolediide (CEJ 2021) to expand and develop the synthetic route to access a range of related ligands and explore their coordination chemistry. Full details |
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October 2023
We welcome two new members to the group. Ben joins us from the University of Edinburgh (M.Sc. Cowley group) to start his Ph.D. research. His project will build on some of our work with conjugated organometallics featuring low-coordinate phosphorus, expanding the concept to include other main group elements. Euritz joins us for her MChem project, having returned from a year in industry. Her project will be focussed on developig new ligand/metal scaffolds to stabilise some of our novel phosphacarbon ligands. A warm welcome to them both. |
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April 2023
Monte and Ian attended the 2023 Dalton meeting in Warwick, where Monte presented a poster of some of our recent work. It was also good to catch up with some past (and future) Crossley lab members |
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