Journal Articles

Latest

1. Levis, M.C.; Helm, M.L. ; Turner, J.F.C.; Crossley, I.R.
   Chem. Eur. J., e202303370 accepted
   "A Monometallic Bis(Cyaphido) Complex"
   Highlighted in ChemistryViews Magazine
2. Pearce, K.G.; Canham, E.P.F.; Nixon, J.F.; Crossley, I.R.
   Chem. Eur. J., 2021, 27, 16242 - 16246
   "A Diphosphaborolediide"
   Highlighted in ChemistryViews Magazine
3. Pearce, K.G.; Crossley, I.R.
   J. Org. Chem., 2020, 85, 14697 - 14707
   "Diphosphametacyclophanes: Structural and Electronic Influences of Substituent Variation within a Family of Bis(diketophosphanyl) Macrocycles"
4. Pearce, K.G.; Simenok, V.; Crossley, I.R.
   Dalton Trans., 2020, 49, 5482 - 5492
   "Phosphacycloalkyldiones: synthesis and coordinative behaviour of 6- and 7-member cyclic diketophosphanyls"
5. Levis, M.C.; Pearce, K.G.; Crossley, I.R.
   Inorg. Chem., 2019, 58, 14800 - 14807
   "Controlled Reactivity of a Terminal Cyaphide Complex: Isolation of the 5-coordinate [Ru(dppe)₂(C≡P)]⁺"
6. Furfari, S.K.; Leech, M.C.; Trathen, N.; Levis, M.C.; Crossley, I.R.
   Dalton Trans., 2019, 48, 8131 - 8143
   "Cyaphide-alkynyl complexes: Metal-ligand conjugation and the influence of remote substituents"
7. Leech, M.C.9 Crossley, I.R.
   Dalton Trans., 2018, 47, 4428 - 4432
   "Through-conjugation of two phosphaalkyne ('C≡P') moieties mediated by a bimetallic scaffold"
8. Greenacre, V.K.; Day, I.J.; Crossley, I.R.
   Organometallics, 2017, 36, 435 - 442
   "Hydrochlorination of Ruthenaphosphaalkenyls: Unexpectedly Facile Access to Alkylchlorohydrophosphane Complexes"

Journal Articles 2011-2016 (11)

9. Greenacre, V.K.; Crossley, I.R.
   Inorganics 2016 4, 30:1-11
   "η¹:η²-P-pyrazolylphosphaalkene Complexes of Ruthenium(0)"
10. Saunders, A.J.; Crossley, I.R.; Roe, S.M.
    Eur. J. Inorg. Chem., 2016, 4076 - 4082
    "Aroylphosphanes: Base-free Synthesis and Their Coordination Chemistry with Platinum Group Metals"
11. Saunders, A.J.; Crossley, I.R.
    Dalton Trans., 2016, 45, 2148 - 2155
    "Synthesis of 3-stannyl and 3-silyl propargyl phosphanes and the formation of a phosphinoallene"
    
12. Greenacre, V.K.; Trathen, N.; Crossley, I.R.
    Organometallics, 2015, 34, 2533 - 2542
    "Ruthenaphosphaalkenyls: Synthesis, structures and their conversion to η²-phosphaalkene complexes"
    
13. Greenacre, V.K.; Ansell, M.B.; Roe, S.M.; Crossley, I.R.
    Eur. J. Inorg. Chem. 2014, 5053 - 5062
    "Synthesis, Structures and Coordination Chemistry of Singly Bridged Phosphane-Boranes with Coordinately Unsatruated Platinum Group Metals"
    
14. Trathen, N.; Leech, M.C.; Crossley, I.R.; Greenacre, V.K., Roe, S.M.
    Dalton Trans. 2014, 43, 9004 - 9007
    "Synthesis and electronic structure of the first cyaphide-alkynyl complexes"
15. Trathen, N.; Greenacre, V.K.; Crossley, I.R.; Roe, S.M.
    Organometallics, 2013, 32, 2501 - 2504
    "Ambiphilic Reactivity of a Ruthenaphosphaalkenyl: Synthesis of P-pyrazolylphosphaalkene Complexes of Ruthenium(0)"
16. Crossley, I.R.; Hayes, J.
    J. Organomet. Chem. 2012, 716, 285 - 288
    "Bis(methimazolyl)borate chemistry of palladium and platinum"
17. Saunders, A.J.; Crossley, I.R.; Coles, M.P.; Roe, S.M
    Chem. Commun. 2012, 48, 5766 - 5768
    "Facile self assembly of the first diphosphametacyclophane"
18. Averre, C.E.; Coles, M.P.; Crossley, I.R.; Day, I.J.
    Dalton Trans. 2012, 41, 278-284
    "The open-chain triphosphanes RMe₂SiCH₂P(PR'₂)₂ (R = Me, Ph; R' = SiMe₃, Cy, Ph)"
    
19. Barnes, N.A.; Brisdon, A.K.; Brown, F.R.W.; Cross, W.I.; Crossley, I.R.; Fish, C.; Herbert, C.J.; Pritchard, R.G.; Warren, J.E.
    Dalton Trans.2011, 40, 1743-1750
    "Synthesis of gold(I) fluoroalkyl and fluoroalkenyl-substituted phosphine complexes and factors affecting their crystal packing"

Journal Articles 2002-2010 (25)

20. Crossley, I.R.; Hill, A.F.; Willis, A.C.
    Organometallics 2010, 29, 326 -336
    "Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls"
21. Al-Ktaifani, M.M.; Coles, M.P.; Crossley, I.R.; Evans, L.T.J.; Hitchcock, P.B.; Lawless, G.A. Nixon. J.F.
    J. Organomet. Chem. 2009, 694, 4223 - 4229
    "Opening 'Jaws'. Functionalisation of the Hexaphosphapentaprismane cage, P₆C₄^tBu₄, affording X₂P₆C₄^tBu₄, (X= Me, I), Crystal and molecular structures of X₂P₆C₄^tBu₄ (X = Me, I) and [cis-PtCl₂Me₂P₆C₄^tBu₄]"
22. Siriwardana, A.I.; Crossley, I.R.; Torriero, A.A.J.; Burgar, I.M.; Dunlop, N.F.; Bond, A.M.; Deacon, G.B.; MarFarlane, D.R.
    J. Org. Chem. 2008, 73, 4676 - 4679
    "Methimazole Based Ionic Liquids"
23. Crossley, I.R.; Foreman, M.R.St.-J.; Hill, A.F.; Owen, G.R.; White, A.J.P.; Williams, D.J.; Willis, A.C.
    Organometallics, 2008, 27, 381 - 386
    "Synthesis of the Ruthenaboratranes [Ru(CS)(PPh₃){B(mt)₃}](Ru→B)⁸ and [Ru(CO)(CNR){B(mt)₃}](Ru→B)⁸ (mt = methimazolyl, R = tBu, C₆H₃Me₂-2,6, C₆H₂Me₃-2,4,6)"
24. Crossley, I.R.; HIll, A.F.; Willis, A.C.
    Organometallics 2008, 27, 312 - 315
    "Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh₃){B(mt)₃}](Pt→B)¹⁰ (mt = Methimazolyl)"
25. Crossley, I.R.; Hill, A.F.; Willis, A.C.
    Dalton Trans., 2008, 201 - 203
    "Unlocking the Metallaboratrane Cage: Reversibile B-H Activation in Platinaboratranes"
26. Crossley, I.R.; Hill, A.F.; Willis, A.C.
    Organometallics 2007, 26, 3891 - 3895
    "Metallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide"
27. Brisdon, A.K.; Crossley, I.R.; Pritchard, R.G.; Sadiq, G.
    J. Organomet. Chem., 2007, 692, 2125 - 2130
    "Asymmetric fluoro-organomercurials part 2. The synthesis and characterisation of the fluorovinyl-mercurials RHgCX=CF₂ (R = Ph, Fc; X = F, Cl): the single crystal X-ray structures of PhHgCF=CF₂, FcHgCF=CF₂ and FcHgCCl=CF₂."
28. Crossley, I.R.; Hill, A.F.; Humphrey, E.R.; Smith, M.K.
    Organometallics 2006, 25, 2242 - 2247
    "A Less Carbocentric View of Agostic Interactions: The Complexes [Rh(η⁴-cod){H₂A(mt)₂}] (A = B, C⁺; mt = methimazolyl)
29. Crossley, I.R.; Hill, A.F.; Willis, A.C.
    Organometallics 2006, 25, 289 - 299
    "Metallaboratranes: Tris(methimazolyl)borane Complexes of Rhodium(I)"
30. Crossley, I.R.; Hill, A.F.; Willis, A.C.
    Organometallics 2005, 24, 4889 - 4892
    "Poly(methimazolyl)borate Complexes of Platinum"
31. Brisdon, A.K.; Crossley, I.R.; Pritchard, R.G.
    Organometallics 2005, 24, 5487 - 5490
    "Asymmetric Fluoro-alkynyl Mercurials: The Synthesis and Solid State Structures of RHgC≡CCF₃(R = Ph, Fc)"
32. Crossley, I.R.; Hill, A.F.; Humphrey, E.R.; Willis, A.C.
    Organometallics 2005, 24, 4083 - 4086
    "The First Bimetallic Metallaboratrane: [Rh₂{B(mt)₃}₂{κ²-S,S'-HB(mt)₃}]Cl and its Synthesis From The Fluxional Rhodaboratrane Salt [Rh{B(mt)3}(η⁴-C₈H₁₂)]Cl, (Rh→B, mt = methimazolyl)"
33. Crossley, I.R.; Hill, A.F.; Willis, A.C.
    Organometallics 2005, 24, 1062 - 1064
    "Metallaboratranes - The Missing Link: The First Iridaboratranes [IrH(CO)(PPh₃){κ³-B,S,S'-B(mt)₂R}] (Ir→B; mt = methimazolyl, R = mt, H)"
34. Crossley, I.R.; Foreman, M.R.St-J.; Hill, A.F.; White, A.J.P.; Williams, D.J.
    Chem. Commun., 2005, 221 - 223
    "The First Rhodaboratrane: [RhCl(PPh₃){B(mt)₃}] (Rh→B) (mt = methimazolyl)"
35. Crossley, I.R.; Hill, A.F.
    Organometallics 2004, 23, 5656 - 5658
    "Di- and Zerovalent Platinaboratranes: The First Pentacoordinate d¹⁰ Platinum(0) Complex."
36. Crossley, I.R.; Hill, A.F.; Humphrey, E.R.; Smith, M.K.; Tshabang, N.; Willis, A.C.
    Chem. Commun., 2004, 1878 - 1879
    "Caveats for poly(methimazolyl)borate chemistry: the novel inorganic heterocycles [H₂C(mt)₂BR₂]Cl (mt = methimazolyl; BR₂ = BH₂, BH(mt), 9-BBN)
37. Barnes, N.A.; Brisdon, A.K.; Crossley, I.R.; Pritchard, R.G.; Warren, J.E.
    Organometallics, 2004, 23, 2680 - 2685
    "Synthesis, Structure and Solution Behaviour of 1-Chloro-2,2-difluorovinyl Titanocene Derivatives: The First X-ray Study of a Titanium Fluorovinyl Compound and Spectroscopic Elucidation of the [Cp₂TiMe(η²-CF₂=CClH)] Complex."
38. Barnes, N.A.; Brisdon, A.K.; Brown, F.R.W.; Cross, W.I.; Crossley, I.R.; Fish, C.; Morey, J.V.; Pritchard, R.G.
    New J. Chem., 2004, 28, 828 - 837
    "The synthesis and chemistry of fluorovinyl-containing phosphines, and the single crystal X-ray structure of SPPrⁱ₂(CF=CF₂)."
39. Brisdon, A.K.; Crossley, I.R.; Greenall, J.A.; Pritchard, R.G.; Warren, J.E.
    J. Fluorine Chem., 2004, 125, 1099 - 1103
    "The Synthesis and Structural Characterisation of an Homologous Series of Group 14 1-Chloro-2,2-difluorovinyl Compounds."
40. Brisdon, A.K.; Crossley, I.R.; Pritchard, R.G.; Sadiq, G.; Warren, J.E.
    Organometallics, 2003, 22, 5534 - 5542
    "Preparation and Functionalization of a Range of Main-Group Trifluoropropynyl Organometallic Compounds: The Application of Metalloid-Directed Carbolithiation to the Selective Synthesis of Novel Fluorocarbon Fragments."
41. Brisdon, A.K.; Crossley, I.R.; Pritchard, R.G.; Warren, J.E.
    Acta Cryst. C, 2003, 59, m322 - m324
    "Tricarbonyl(η⁶-chlorobenzene)-chromium"
42. Brisdon, A.K.; Crossley, I.R.; Flower, K.R.; Pritchard, R.G.; Warren, J.E.
    Angew. Chem. Int. Ed. 2003, 42, 2399 -2401
    "Ringing the Changes: A Remarkable Carbene-Free Synthesis of Difluorocyclopropenes."
43. Brisdon, A.K.; Crossley, I.R.
    Chem. Commun. 2002, 2420 - 2421
    "Hydrofluorocarbon 245fa: A Versatile New Synthon in Alkyne Chemistry"
44. Brisdon, A.K.; Crossley, I.R.; Pritchard, R.G.; Warren, J.E.
    Inorg. Chem., 2002, 41, 4748 - 4755
    "Spectroscopic and Structural Assignment of the Absolute Stereochemistry in a Series of 1,2-difluorovinyl Organometalloids. The first Crystallographic Characterization and Structural Series of Group 14 Fluorovinyl Compounds."

Book Chapters and Reviews (4)

1. Crossley, I.R.
   Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2013, 109, 200 - 207
   "Zinc, Cadmium and Mercury"
2. Crossley, I.R.
   Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2012, 108, 244 - 250
   "Zinc, Cadmium and Mercury"
3. Crossley, I.R.
   Adv. Organomet. Chem. 2010, 58, 109 - 208
   "Organometallic Chemistry of Group 10 Poly(pyrazolyl)borate Complexes"
4. Crossley, I.R.
   Adv. Organomet. Chem. 2008, 56, 199 - 321
   "Organometallic Chemistry of Group 9 Poly(pyrazolyl)borate Complexes"