Brown Lab

Publications

2023

  • Balucani, N., Bertin, M., Brann, M., Brown, W., Ceccarelli, C., Martín-Doménech, R., . . . al., E. (2023). Laboratory astrochemistry of and on dust and ices: general discussion. Faraday Discussions, 245, 519-540. doi:10.1039/d3fd90026f
    Article. View on figshare.
  • Ingman, E. R., Laurinavicius, D., Zhang, J., Schrauwen, J., Redlich, B., Noble, J., . . . Brown, W. (n.d.). Infrared photodesorption of CO from astrophysically relevant ices studied with a free-electron laser. Faraday Discussions, pages. doi:10.1039/D3FD00024A
    Article. View on figshare.
  • Fulker, J., Gutiérrez-Quintanilla, A., Brown, W., Pino, G. A., Hacquard, A., Niedojadlo, A., & Noble, J. A. (n.d.). Gas phase electronic spectra of xylene-water aggregates. Journal of Molecular Spectroscopy, a111761 ( pages). doi:10.1016/j.jms.2023.111761
    Article. View on figshare.
  • McClure, M. K., Rocha, W. R. M., Pontoppidan, K. M., Crouzet, N., Chu, L. E. U., Dartois, E., . . . others. (n.d.). An Ice Age JWST inventory of dense molecular cloud ices. Nature Astronomy, pages. doi:10.1038/s41550-022-01875-w
    Article. View on figshare.

2022

  • Minissale, M., Aikawa, Y., Bergin, E., Bertin, M., Brown, W., Cazaux, S., . . . Dulieu, F. (2022). Thermal desorption of interstellar ices: a review on the controlling parameters and their implications from snowlines to chemical complexity. ACS Earth and Space Chemistry, 6(3), 597-630. doi:10.1021/acsearthspacechem.1c00357
    Article. View on figshare.

2021

  • Ingman, E. R., Shepherd, A., & Brown, W. (n.d.). Using surface science techniques to investigate the interaction of acetonitrile with dust grain analogue surfaces. Johnson Matthey Technology Review, pages. doi:10.1595/205651321X16264409352535
    Article. View on figshare.
  • Salter, T. L., Stubbing, J., Brigham, L., & Brown, W. (2021). Using laboratory investigations to aid the identification of small aromatic molecules in water-containing astrophysical ices. Frontiers in Astronomy and Space Sciences, 8, 1-11. doi:10.3389/fspas.2021.644277
    Article. View on figshare.

2020

  • Stubbing, J., McCoustra, M. R. S., & Brown, W. (n.d.). A new technique for determining the refractive index of ices at cryogenic temperatures. Physical Chemistry Chemical Physics, pages. doi:10.1039/D0CP02373F
    Article. View on figshare.

2019

  • Salter, T. L., Wootton, L., & Brown, W. (2019). Thermal processing and interactions of ethyl formate in model astrophysical ices containing water and ethanol. ACS Earth and Space Chemistry, 3(8), 1524-1536. doi:10.1021/acsearthspacechem.9b00091
    Article. View on figshare.

2018

  • Salter, T. L., Stubbing, J., Brigham, L., & Brown, W. (n.d.). A TPD and RAIRS comparison of the low temperature behavior of benzene, toluene, and xylene on graphite. The Journal of Chemical Physics, 149(164705), 1-11. doi:10.1063/1.5051134
    Article. View on figshare.
  • Stubbing, J., Salter, T. L., Brown, W., Taj, S., & McCoustra, M. R. S. (n.d.). A fibre-coupled UHV-compatible variable angle reflection-absorption UV/visible spectrometer. Review of Scientific Instruments, 89(054102), 1-6. doi:10.1063/1.5025405
    Article. View on figshare.

2017

  • Ayling, S. A., Burke, D. J., Salter, T. L., & Brown, W. (n.d.). Desorption and crystallisation of binary 2-propanol and water ices adsorbed on graphite. RSC Advances, 2017(7), 51621-51631. doi:10.1039/C7RA10410C
    Article. View on figshare.

2016

  • Rosu-Finsen, A., Marchione, D., Salter, T. L., Stubbing, J., Brown, W., & McCoustra, M. R. S. (2016). Peeling the astronomical onion. Physical Chemistry Chemical Physics, 18(46), 31930-31935. doi:10.1039/C6CP05751A
    Article. View on figshare.
  • Butorac, J., Wilson, E. L., Fielding, H. H., Brown, W., & Minns, R. S. (n.d.). A RAIRS, TPD and femtosecond laser-induced desorption study of CO, NO and coadsorbed CO + NO on Pd(111). RSC Advances, 6, 66346-66359. doi:10.1039/C6RA13722A
    Article. View on figshare.
  • Brown, W. (2016). Adsorption and processing of complex organic molecules on dust grains. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 252. Retrieved from https://www.webofscience.com/
    Conference publication.

2015

  • Burke, D. J., Puletti, F., Woods, P. M., Viti, S., Slater, B., & Brown, W. (2015). Trapping and desorption of complex organic molecules in water at 20 K. The Journal of Chemical Physics, 143, pages. doi:10.1063/1.4934264
    Article. View on figshare.
  • Burke, D. J., & Brown, W. (2015). The effects of methanol on the trapping of volatile ice components. Monthly Notices of the Royal Astronomical Society, 448(2), 1807-1815. doi:10.1093/mnras/stv109
    Article. View on figshare.
  • Burke, D. J., Puletti, F., Woods, P. M., Viti, S., Slater, B., & Brown, W. (2015). Adsorption and thermal processing of glycolaldehyde, methyl formate, and acetic acid on graphite at 20 K. The Journal of Physical Chemistry A, 119(26), 6837-6849. doi:10.1021/acs.jpca.5b04010
    Article. View on figshare.

2014

  • Burke, D. J., Puletti, F., Brown, W., Woods, P. M., Viti, S., & Slater, B. (2015). Glycolaldehyde, methyl formate and acetic acid adsorption and thermal desorption from interstellar ices. Monthly Notices of the Royal Astronomical Society, 447(2), 1444-1451. doi:10.1093/mnras/stu2490
    Article. View on figshare.
  • Brown, W., Occhiogrosso, A., Vasyunin, A., Herbst, E., Viti, S., Ward, M. D., & Price, S. D. (2014). Ethylene oxide and acetaldehyde in hot cores. Astronomy and Astrophysics, 564, pages. doi:10.1051/0004-6361/201322598
    Article. View on figshare.
  • Brown, W. (2014). Astrochemistry. Physical Chemistry Chemical Physics, 16, 3343 ( pages). doi:10.1039/c4cp90004a
    Article. View on figshare.

2013

  • Woods, P. M., Slater, B., Raza, Z., Viti, S., Brown, W., & Burke, D. J. (2013). Glycolaldehyde formation via the dimerization of the formyl radical. The Astrophysical Journal, 777(2), 90 ( pages). doi:10.1088/0004-637X/777/2/90
    Article. View on figshare.
  • Edridge, J. L., Freimann, K., Burke, D. J., & Brown, W. (2013). Surface science investigations of the role of CO2 in astrophysical ices. Philosophical Transactions A: Mathematical, Physical and Engineering Sciences, 371(1994), pages. doi:10.1098/rsta.2011.0578
    Article. View on figshare.

2012

  • Woods, P. M., Kelly, G., Viti, S., Slater, B., Brown, W., Puletti, F., . . . Raza, Z. (2012). On the formation of glycolaldehyde in dense molecular cores. Astrophysical Journal, 750(1), pages. doi:10.1088/0004-637X/750/1/19
    Article. View on figshare.

2010

  • Thrower, J. D., Abdulgalil, A. G. M., Collings, M. P., McCoustra, M. R. S., Burke, D. J., Brown, W. A., . . . Rutten, F. J. M. (2010). Photon- and electron-stimulated desorption from laboratory models of interstellar ice grains. In Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films Vol. 28 (pp. 799-806). doi:10.1116/1.3336466
    Conference publication. View online.
  • Adriaens, D. A., Goumans, T. P. M., Catlow, C. R. A., & Brown, W. (2010). Computational study of carbonyl sulphide formation on model interstellar dust grains. Journal of Physical Chemistry C, 114(4), 1892-1900. doi:10.1021/jp9083212
    Article. View on figshare.
  • Burke, D. J., & Brown, W. (2010). Ice in space: surface science investigations of the thermal desorption of model interstellar ices on dust grain analogue surfaces. Physical Chemistry Chemical Physics, 12(23), 5947-5969. doi:10.1039/b917005g
    Article. View on figshare.
  • Wilson, E. L., & Brown, W. (2010). Low Pressure RAIRS Studies of Model Catalytic Systems. Journal of Physical Chemistry C, 114(15), 6879-6893. doi:10.1021/jp912080t
    Article. View on figshare.

2009

  • Goumans, T. P., Catlow, C. R. A., Brown, W., Kastner, J., & Sherwood, P. (2009). An embedded cluster study of the formation of water on interstellar dust grains. Physical Chemistry Chemical Physics, 11(26), 5431-5436. doi:10.1039/b816905e
    Article. View on figshare.
  • Goumans, T. P. M., Richard, C., Catlow, A., & Brown, W. (2009). Formation of H-2 on an olivine surface: a computational study. Monthly Notices of the Royal Astronomical Society, 393(4), 1403-1407. doi:10.1111/j.1365-2966.2008.14155.x
    Article. View on figshare.
  • Green, S. D., Bolina, A. S., Chen, R., Collings, M. P., Brown, W., & McCoustra, M. R. S. (2009). Applying laboratory thermal desorption data in an interstellar context: sublimation of methanol thin films. Monthly Notices of the Royal Astronomical Society, 398(1), 357-367. doi:10.1111/j.1365-2966.2009.15144.x
    Article. View on figshare.

2008

  • Wilson, E. L., Grau-Crespo, R., Pang, C. L., Cabailh, G., Chen, Q., Purton, J. A., . . . Thornton, G. (2008). Redox behavior of the model catalyst Pd/CeO2-x/Pt(111). Journal of Physical Chemistry C, 112(29), 10918-10922. doi:10.1021/jp8004103
    Article. View on figshare.
  • Goumans, T. P. M., Uppal, M. A., & Brown, W. (2008). Formation of CO2 on a carbonaceous surface: a quantum chemical study. Monthly Notices of the Royal Astronomical Society, 384(3), 1158-1164. doi:10.1111/j.1365-2966.2007.12788.x
    Article. View on figshare.
  • Burke, D. J., Wolff, A. J., Edridge, J. L., & Brown, W. (2008). The adsorption and desorption of ethanol ices from a model grain surface. Journal of Chemical Physics, 128(10), pages. doi:10.1063/1.2888556
    Article. View on figshare.
  • Burke, D. J., Wolff, A. J., Edridge, J. L., & Brown, W. (2008). Thermally induced mixing of water dominated interstellar ices. Physical Chemistry Chemical Physics, 10(32), 4956-4967. doi:10.1039/b807220e
    Article. View on figshare.
  • Goumans, T. P. M., Catlow, C. R. A., & Brown, W. (2008). Catalysis of addition reactions by a negatively charged silica surface site on a dust grain. Journal of Physical Chemistry C, 112(39), 15419-15422. doi:10.1021/jp8042297
    Article. View on figshare.
  • Goumans, T. P. M., Catlow, C. R. A., & Brown, W. (2008). Hydrogenation of CO on a silica surface: an embedded cluster approach. Journal of Chemical Physics, 128(13), pages. doi:10.1063/1.2888933
    Article. View on figshare.
  • Thrower, J. D., Burke, D. J., Collings, M. P., Dawes, A., Holtom, P. D., Jamme, F., . . . Parker, A. W. (2008). Desorption of hot molecules from photon irradiated interstellar ices. Astrophysical Journal, 673(2), 1233-1239. doi:10.1086/524097
    Article. View on figshare.
  • Thrower, J. D., Collings, M. P., McCoustra, M. R. S., Burke, D. J., Brown, W., Dawes, A., . . . Parker, A. W. (2008). Surface science investigations of photoprocesses in model interstellar ices. Journal of Vacuum Science and Technology A, 26(4), 919-924. doi:10.1116/1.2834687
    Article. View on figshare.

2007

  • Wilson, E. L., Chen, Q., Brown, W., & Thornton, G. (2007). CO adsorption on the model catalyst Pd/CeO2-x(111)/Rh(111). Journal of Physical Chemistry C, 111(38), 14215-14222. doi:10.1021/jp0737449
    Article. View on figshare.
  • Brown, W., & Bolina, A. S. (2007). Fundamental data on the desorption of pure interstellar ices. Monthly Notices of the Royal Astronomical Society, 374(3), 1006-1014. doi:10.1111/j.1365-2966.2006.11216.x
    Article. View on figshare.
  • Goumans, T. P. M., Wander, A., Brown, W., & Catlow, C. R. A. (2007). Structure and stability of the (001) alpha-quartz surface. Physical Chemistry Chemical Physics, 9(17), 2146-2152. doi:10.1039/B701176H
    Article. View on figshare.
  • Goumans, T. P. M., Wander, A., Catlow, C. R. A., & Brown, W. (2007). Silica grain catalysis of methanol formation. Monthly Notices of the Royal Astronomical Society, 382(4), 1829-1832. doi:10.1111/j.1365-2966.2007.12491.x
    Article. View on figshare.
  • Williams, D. A., Brown, W., Price, S. D., Rawlings, J. M. C., & Viti, S. (2007). Molecules, ices and astronomy. Astronomy and Geophysics, 48(1), pages. doi:10.1111/j.1468-4004.2007.48125.x
    Article. View on figshare.
  • Wolff, A. J., Carlstedt, C., & Brown, W. (2007). Studies of binary layered CH3OH/H2O ices adsorbed on a graphite surface. Journal of Physical Chemistry C, 111(16), 5990-5999. doi:10.1021/jp067377x
    Article. View on figshare.

2006

  • Wilson, E. L., Brown, W., & Thornton, G. (2006). RAIRS studies of CO adsorption on Pd/CeO2-x(111)/Pt(111). Surface Science, 600(12), 2555-2561. doi:10.1016/j.susc.2006.04.020
    Article. View on figshare.
  • Brown, W., Viti, S., Wolff, A. J., & Bolina, A. S. (2006). Laboratory investigations of the role of the grain surface in astrochemical models. Faraday Discussions, 133, 113-124. doi:10.1039/b516770a
    Article. View on figshare.

2005

  • McCoustra, M. R. S., Brown, W., & Viti, S. (2005). To infinity and beyond. Education in Chemistry, 42, 153-155.
    Article. View on figshare.
  • Bolina, A. S., Wolff, A. J., & Brown, W. (2005). Reflection absorption infrared spectroscopy and temperature-programmed desorption studies of the adsorption and desorption of amorphous and crystalline water on a graphite surface. Journal of Physical Chemistry B, 109(35), 16836-16845. doi:10.1021/jp0528111
    Article. View on figshare.
  • Bolina, A. S., Wolff, A. J., & Brown, W. (2005). Reflection absorption infrared spectroscopy and temperature programmed desorption investigations of the interaction of methanol with a graphite surface. Journal of Chemical Physics, 122(4), 044713-1. doi:10.1063/1.1839554
    Article. View on figshare.
  • Bolina, A. S., & Brown, W. (2005). Studies of physisorbed ammonia overlayers adsorbed on graphite. Surface Science, 598(1-3), 45-56. doi:10.1016/j.susc.2005.08.025
    Article. View on figshare.

2004

  • Viti, S., Brown, W., McCoustra, M., Fraser, H., Mason, N., & Massey, R. (2004). Public understanding: the making of Stars `R' Us!. Astronomy and Geophysics, 45(6), 6.22-6.24. doi:10.1046/j.1468-4004.2003.45622.x
    Article. View on figshare.
  • Mukerji, R. J., Bolina, A. S., Brown, W., Liu, Z. -P., & Hu, P. (2004). The temperature dependence of the adsorption of NO on Pt{211}: A RAIRS and DFT investigation. Journal of Physical Chemistry B, 108(1), 289-296. doi:10.1021/jp030460p
    Article. View on figshare.
  • Viti, S., McCoustra, M., Brown, W., Mason, N., Fraser, H., & Massey, R. (2004). Stars 'R' Us!. ASTRONOMY & GEOPHYSICS, 45(5), 4. doi:10.1093/astrogeo/45.5.5.4-a
    Article. View online.

2003

  • Mukerji, R. J., Bolina, A. S., & Brown, W. (2003). An investigation of the effect of pre-dosed O atoms on the adsorption of NO on Pt{211}. Surface Science, 547(1-2), 27-44. doi:10.1016/j.susc.2003.09.034
    Article. View on figshare.
  • Creighan, S. C., Mukerji, R. J., Bolina, A. S., Lewis, D. W., & Brown, W. (2003). The adsorption of CO on the stepped Pt{211} surface: a comparison of theory and experiment. Catalysis Letters, 88(1-2), 39-45. doi:10.1023/A:1023582732207
    Article. View on figshare.
  • Mukerji, R. J., Bolina, A. S., & Brown, W. (2003). A RAIRS and TPD investigation of the adsorption of CO on Pt{211}. Surface Science, 527(1-3), 198-208. doi:10.1016/S0039-6028(03)00027-X
    Article. View on figshare.
  • Mukerji, R. J., Bolina, A. S., & Brown, W. (2003). The influence of steps on the dissociation of NO on Pt surfaces: Temperature-programmed desorption studies of NO adsorption on Pt{211}. Journal of Chemical Physics, 119(20), 10844-10852. doi:10.1063/1.1619940
    Article. View on figshare.
  • Brown, W. (2003). No, CN, O2 on metals. In Physics of covered solid surfaces (pp. 302-361). Springer Verlag.
    Chapter. View on figshare.

2000

  • Brown, W., & King, D. A. (2000). NO chemisorption and reactions on metal surfaces: A new perspective. Journal of Physical Chemistry B, 104(12), 2578-2595. doi:10.1021/jp9930907
    Article. View on figshare.

1999

  • Kose, R., Brown, W., & King, D. A. (1999). Determination of the Rh-C bond energy for C2H2 and C2H4 reactive adsorption on Rh{100}. Chemical Physics Letters, 311(3-4), 109-116. doi:10.1016/S0009-2614(99)00817-9
    Article. View on figshare.
  • Kose, R., Brown, W., & King, D. A. (n.d.). Calorimetric heats of dissociative adsorption for O-2 on Rh{100}. Surface Science, 402-4, 856-860. doi:10.1016/S0039-6028(97)01027-3
    Article. View on figshare.
  • Kose, R., Brown, W., & King, D. A. (1999). Energetics and kinetics of step-terrace adsorbate distribution: C2H2 on Pt{211}. Journal of the American Chemical Society, 121(20), 4845-4851. doi:10.1021/ja9834475
    Article. View on figshare.
  • Brown, W., Kose, R., & King, D. A. (1999). The role of adsorption heats and bond energies in the assignment of surface reaction products: ethyne and ethene on Ni{110}. Journal of Molecular Catalysis A: Chemical, 141(1-3), 21-29. doi:10.1016/S1381-1169(98)00246-5
    Article. View on figshare.
  • Brown, W., Ge, Q., Sharma, R. K., & King, D. A. (1999). Lateral potential energy surfaces for molecular chemisorption on metals from experiment and theory: NO on Pt{110}-(1x2). Chemical Physics Letters, 299(3-4), 253-259. doi:10.1016/S0009-2614(98)01272-X
    Article. View on figshare.
  • Brown, W., Kose, R., & King, D. A. (1999). Calorimetric measurements of the adsorption heat for ethene on Pt{211} and Pt{311}. Surface Science, 440(1-2), 271-278. doi:10.1016/S0039-6028(99)00814-6
    Article. View on figshare.
  • Brown, W., Sharma, R. K., Ge, Q., & King, D. A. (1999). Multilayer influences on the monolayer structure for NO on Pt{110}-(1x2). Physical Chemistry Chemical Physics, 1(8), 1995-2000. doi:10.1039/A900850K
    Article. View on figshare.
  • Kose, R., Brown, W., & King, D. A. (1999). Role of lateral interactions in adsorption kinetics: CO/Rh{100}. Journal of Physical Chemistry B, 103(41), 8722-8725. doi:10.1021/jp991339e
    Article. View on figshare.
  • Ge, Q., Brown, W., Sharma, R. K., & King, D. A. (1999). NO monomer and (NO)(x) polymeric chain chemisorption on Pt{110}: Structure and energetics. Journal of Chemical Physics, 110(24), 12082-12088. doi:10.1063/1.479143
    Article. View on figshare.

1998

  • Sharma, R. K., Brown, W., & King, D. A. (1998). The adsorption of CO on Pt{110} over the temperature range from 90 to 300 K studied by RAIRS. Surface Science, 414(1-2), 68-76. doi:10.1016/S0039-6028(98)00467-1
    Article. View on figshare.
  • Sharma, R. K., Brown, W., & King, D. A. (1998). Adsorbed CO chain condensation and evaporation on Pt{110}-(1 x 2) at 30-70 K studied by RAIRS. Chemical Physics Letters, 291(1-2), 1-6. doi:10.1016/S0009-2614(98)00594-6
    Article. View on figshare.
  • Brown, W., Sharma, R. K., & King, D. A. (1998). Site switching and surface restructuring induced by NO adsorption on Pt{110}. Journal of Physical Chemistry B, 102(27), 5303-5308. doi:10.1021/jp981061a
    Article. View on figshare.
  • Brown, W., Kose, R., & King, D. A. (1998). Femtomole adsorption calorimetry on single-crystal surfaces. Chemical Reviews, 98(2), 797-832. doi:10.1021/cr9700890
    Article. View on figshare.

1996

  • Brown, W., Sharma, R. K., King, D. A., & Haq, S. (1996). Adsorption and reactivity of NO and N2O on Cu{110}: Combined RAIRS and molecular beam studies. Journal of Physical Chemistry, 100(30), 12559-12568. doi:10.1021/jp9602888
    Article. View on figshare.

1995

  • Brown, W., Sharman, R. K., Gardner, P., King, D. A., & Martin, D. H. (1995). The design of a super-sensitive infrared-emission spectrometer for studies of adsorbate dynamics. Surface Science, 331-3(Part B), 1323-1328. doi:10.1016/0039-6028(95)00195-6
    Article. View on figshare.
  • Brown, W., Gardner, P., Jigato, M. P., & King, D. A. (1995). Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures. Journal of Chemical Physics, 102(18), 7277-7280. doi:10.1063/1.469039
    Article. View on figshare.
  • Brown, W., Gardner, P., & King, D. A. (1995). The adsorption of NO² on AG{111} - a low-temperature RAIRS study. Surface Science, 330(1), 41-47. doi:10.1016/0039-6028(95)00397-5
    Article. View on figshare.
  • Brown, W., Gardner, P., & King, D. A. (1995). VERY-LOW TEMPERATURE SURFACE-REACTION - N2O FORMATION FROM NO DIMERS AT 70 TO 90 K ON AG(111). Journal of Physical Chemistry, 99(18), 7065-7074. doi:10.1021/j100018a045
    Article. View on figshare.

Unpublished works

  • Noble, J. A., Fraser, H. J., Smith, Z. L., Dartois, E., Boogeert, A. C. A., Cuppen, H. C., . . . al., E. (n.d.). Detection of the elusive dangling OH ice features at ∼ 2.7 µm in Chamaeleon I with JWST NIRCam. Nature Astronomy, pages. doi:10.1038/s41550-024-02307-7
    Article. View on figshare.